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Phenobarbital is 5-ethyl-5-phenylbarbituric acid. Phenobarbital is usually a substituted pyrimidine by-product where the basic structure is barbituric acid, a material that has no CNS activity. CNS activity is received by substituting alkyl, alkenyl, or aryl teams over the pyrimidine ring. It's the next structural components:Phenytoin, Sodium Valpr